MATERIAL SAFETY DATA SHEET
Quali-Pro® Propiconazole 14.3
Page 1 of 4
2-18-09
1. IDENTIFICATION
Product name: Quali-Pro® Propiconazole 14.3
Chemical name of active ingredient(s): Propiconazole: 1-[[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-
2-yl]Methyl]-1H-1,2,4-triazole
Manufacturer: FarmSaver.com, LLC.
4515 Falls of Neuse Road, Suite 300
Raleigh, NC 27609
Phone: 1-800-979-8994
For fire, spill, and/or leak emergencies, contact
Chemtrec:
Phone: 1-800-424-9300
Outside US: 1-703-527-3887
For medical emergencies and health and
safety inquiries, contact Prosar: Phone: 1-800-308-5391
2. COMPOSITION/INFORMATION ON INGREDIENTS
COMMON NAME CAS NO. % OSHA PEL ACGIH TLV OTHER
NTP/IARC/OSHA
(Carcinogen)
Propiconazole 60207-90-1 14.3 NA NA NA NA
NA=Not applicable
3. HAZARDS IDENTIFICATION
PHYSICAL PROPERTIES:
Appearance: Clear amber liquid.
Odor: Slight solvent odor.
EMERGENCY OVERVIEW: Warning. Causes substantial, but temporary eye injury. Do not get in eyes or on
clothing. Harmful if swallowed, inhaled, or absorbed through skin. Avoid contact with skin or clothing. Avoid
breathing vapor or spray mist.
PHYSICAL OR CHEMICAL HAZARDS: Do not use or store near heat or open flame.
HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce toxic carbon and nitrogen
oxides, and hydrogen chloride.
PRIMARY ROUTES OF EXPOSURE: Eye, skin, ingestion and inhalation.
4. FIRST AID
FIRST AID
•Hold eye open and rinse slowly and gently with water for 15 to 20 minutes.
•Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye.
IF IN EYES:
•Call a poison control center or doctor for treatment advice.
•Take off contaminated clothing.
•Rinse skin immediately with plenty of water for 15 to 20 minutes.
IF ON SKIN OR
CLOTHING:
•Call a poison control center or doctor for treatment advice.
•Immediately call a poison control center or doctor.
•Do not give any liquid to the person.
•Do not induce vomiting unless told to do so by a poison control center or doctor.
IF SWALLOWED:
•Do not give anything by mouth to an unconscious person.
•Move person to fresh air.
•If person is not breathing, call 911 or an ambulance, then give artificial respiration,
preferably mouth-to-mouth if possible.
IF INHALED:
•Call a poison control center or doctor for further treatment advice.
Have the product container or label with you when calling a poison control center or doctor or going for treatment.
For medical emergencies involving this product call 1-800-308-5391.
NOTE TO PHYSICIAN: There is no specific antidote for this product. Induce emesis or lavage stomach, taking
care to avoid aspiration of stomach contents into lungs.
5. FIRE FIGHTING MEASURES
FLASH POINT: 165°F (92^οC) (TCC)
FLAMMABLE LIMITS (LFL-UFL): N/D.
EXTINGUISHING MEDIA: Foam, dry chemical, carbon dioxide, or water spray.
SPECIAL FIRE-FIGHTING PROCEDURES: Evacuate area and fight fire upwind from a safe distance to avoid
hazardous vapors an decomposition products. Foam and/or dry chemical are preferred to minimize environmental
contamination. If water is used, dike and collect water to prevent run off. Wear self-contained breathing apparatus
and full fire-fighting turn-out gear (Bunker gear).
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS: Thermal decomposition may produce toxic carbon
and nitrogen oxides, and hydrogen chloride.
6. ACCIDENTAL RELEASE MEASURES
Clean up spills immediately. Isolate hazard area. Keep unnecessary and unprotected personnel from entering.
SMALL SPILL: Absorb small spills or sand, vermiculite or other inert absorbent. Place contaminated material in
appropriate container for disposal.
LARGE SPILL: Dike large spills using absorbent or impervious material such as clay or sand. Recover and
contain as much free liquid as possible for reuse. Allow absorbed material to solidify, and scrape up for disposal.
Pick up wash liquid with additional absorbent and place in a disposable container. After removal, flush
contaminated area thoroughly with water. This material should be prevented from contaminating soil or from
entering sewage and drainage systems and bodies of water.
7. HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING: Handle and open container in a manner as to prevent spillage.
Do not get on skin or in eyes. Do not eat, drink or smoke during work; wash hands and face thoroughly before
doing so. Immediately wash off accidental splashes of the concentrate or spray mixture from skin, clothing and
out of eyes.
PRECAUTIONS TO BE TAKEN IN STORAGE: To prevent contamination, store this product away from food or
feed.
STORAGE TEMPERATURE (MIN/MAX): Do not store above 150oF(66oC) or below 20oF.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE
INTENDED FOR THE MANUFACTURE, FORMULATION, PACKAGING AND USE OF THIS PRODUCT.
FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT
LABEL.
EYE PROTECTION: Protective goggles or full-face shield.
SKIN PROTECTION: Long-sleeved shirt, long pants, shoes plus socks. Chemical-resistant footwear and overalls.
HAND PROTECTION: Chemical-resistant gloves such as barrier laminate, butyl rubber, nitrile, neoprene rubber,
polyvinyl chloride (PVC), or Viton.
ADDITIONAL PROTECTIVE MEASURES: Discard clothing and other absorbent materials that have been
drenched or heavily contaminated with this product's concentrate. Do not reuse them. Follow manufacturer's
instructions for cleaning and maintaining PPE. If no such instructions for washables, use detergent and hot water.
Keep and wash PPE separately from other laundry.

USER SAFETY RECOMMENDATIONS:
Users should:
•Wash hands before eating, drinking, chewing gum, using tobacco, or using the toilet.
•Remove clothing immediately after handling this product. Wash outside of gloves before removing. As
soon as possible, wash thoroughly and change into clean clothing.
EXPOSURE GUIDELINES: Refer to Section 2.
ENGINEERING CONTROLS: Refer to product label.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Clear amber liquid.
ODOR: Slight solvent odor.
FLASH POINT: 165°F (92^οC)
pH: 5.6-6.0
DENSITY: 1.082
10. STABILITY AND REACTIVITY
STABILITY: Stable under normal conditions.
CONDITIONS TO AVOID: Avoid temperatures above 150oF and below 20oF. Avoid contact with oxidizing alkaline
and acidic conditions and materials.
HAZARDOUS POLYMERIZATION: Will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce toxic carbon and nitrogen
oxides, and hydrogen chloride.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY:
Oral LD50 (rat)-> 3,000 mg/Kg
Dermal LD50 (rat)-> 2,000 mg/Kg
Inhalation LC50 (rat)-> 2.0 mg/L (4-hr)
Eye Irritation (rabbit)-Moderately irritating
Skin Irritation (rabbit)-Slightly irritating
Sensitization (guinea pig)-Not a skin sensitizer
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL HAZARDS: This pesticide is toxic to fish. DO NOT apply directly to water, to areas where
surface water is present, or to intertidal areas below the mean high water mark. DO NOT contaminate water
when disposing of equipment wash water.
13. DISPOSAL CONSIDERATIONS:
END USERS MUST DISPOSE OF ANY UNUSED PRODUCT AS PER THE LABEL RECOMMENDATIONS.
PRODUCT DISPOSAL: Pesticide wastes are toxic. Improper disposal of unused pesticide, spray mixture, or
rinse water is a violation of Federal law. If these wastes cannot be used according to label instructions, contact
your State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA
Regional Office for guidance in proper disposal methods.
CONTAINER DISPOSAL: Dispose of product containers, waste containers, and residues according to label
instructions and local, state, and federal health and environmental regulations.
14. TRANSPORT INFORMATION:
DOT CLASSIFICATION:
Not regulated
INTERNATIONAL TRANSPORTATION:
IMO (vessel): Not regulated
IATA (air): Not regulated

15. REGULATORY INFORMATION:
SARA TITLE III CLASSIFICATION:
Section 302: Not applicable.
Section 311/312: Acute health hazard (immediate)
Delayed health hazard (chronic)
Section 313: Propiconazole CAS #: 60207-90-1 (14.3%)
CA PROPOSITION 65: Not applicable.
CERCLA RQ: Not applicable.
RCRA CLASSIFICATION: Under RCRA, it is the responsibility of the product user to determine at the time of
disposal, whether a material containing the product or derived from the product should be classified as a
hazardous waste.
TSCA STATUS: The ingredients of this product are listed on the TSCA inventory or are exempt.
16. OTHER INFORMATION:
HAZARD RATINGS NFPA
HEALTH: 2 0 MINIMAL
FLAMMABILITY: 1 1 SLIGHT
REACTIVITY: 0 2 MODERATE
3 HIGH
4 SEVERE
MSDS DATE: 2-18-09.
The information contained herein is given in good faith and is believed to be correct, but no warrant, express or
implied, is made. Consult FarmSaver.com, LLC for further information.